A fundamental equation of state for chloroethene for temperatures from the triple point to 430 K and pressures to 100 MPa
- A fundamental equation of state in terms of the Helmholtz energy is presented for chloroethene (vinyl chloride). Due to its fundamental nature, it can be used to consistently calculate all thermodynamic state properties in the fluid region. Based on the underlying experimental database, it is valid from the triple-point temperature 119.31 K to 430 K with a maximum pressure of 100 MPa. In addition to the accurate reproduction of experimental data, correct extrapolation behavior during the development of the equation was attained. This enables the equation to be applied in modern mixture frameworks.
| Author: | Monika TholORCiDGND, Florian FenklGND, Eric W. LemmonGND |
|---|---|
| URN: | urn:nbn:de:hbz:294-86150 |
| DOI: | https://doi.org/10.1007/s10765-021-02961-3 |
| Parent Title (English): | International journal of thermophysics |
| Publisher: | Springer Nature |
| Place of publication: | Berlin |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2022/02/18 |
| Date of first Publication: | 2022/01/10 |
| Publishing Institution: | Ruhr-Universität Bochum, Universitätsbibliothek |
| Tag: | Equation of state; Helmholtz energy; Thermodynamic properties; Vinyl chloride |
| Volume: | 43 |
| Issue: | Article 41 |
| First Page: | 41-1 |
| Last Page: | 41-22 |
| Institutes/Facilities: | Lehrstuhl für Thermodynamik |
| Institut für Thermo- und Fluiddynamik | |
| Dewey Decimal Classification: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften, Maschinenbau |
| open_access (DINI-Set): | open_access |
| Licence (English): |  Creative Commons - CC BY 4.0 - Attribution 4.0 International |
