Erik Troschke, Desirée Leistenschneider, Tilo Rensch, Sven Grätz, Johannes Maschita, Sebastian Ehrling, Benjamin Klemmed, Bettina Valeska Lotsch, Alexander Eychmüller, Lars Borchardt, Stefan Kaskel
- The synthesis of porous electrode materials is often linked with the generation of waste that results from extensive purification steps and low mass yield. In contrast to porous carbons, covalent triazine frameworks (CTFs) display modular properties on a molecular basis through appropriate choice of the monomer. Herein, the synthesis of a new pyridine-based CTF material is showcased. The porosity and nitrogen-doping are tuned by a careful choice of the reaction temperature. An in-depth structural characterization by using Ar physisorption, X-ray photoelectron spectroscopy, and Raman spectroscopy was conducted to give a rational explanation of the material properties. Without any purification, the samples were applied as symmetrical supercapacitors and showed a specific capacitance of 141 F g\(^{−1}\). Residual ZnCl\(_2\), which acted formerly as the porogen, was used directly as the electrolyte salt. Upon the addition of water, ZnCl\(_2\) was dissolved to form the aqueous electrolyte in situ. Thereby, extensive and time-consuming washing steps could be circumvented.
Metadaten| Author: | Erik TroschkeGND, Desirée LeistenschneiderGND, Tilo RenschORCiDGND, Sven GrätzORCiDGND, Johannes MaschitaGND, Sebastian EhrlingGND, Benjamin KlemmedGND, Bettina Valeska LotschGND, Alexander EychmüllerGND, Lars BorchardtORCiDGND, Stefan KaskelORCiDGND |
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| URN: | urn:nbn:de:hbz:294-81781 |
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| DOI: | https://doi.org/10.1002/cssc.202000518 |
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| Parent Title (English): | ChemSusChem |
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| Publisher: | Wiley |
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| Place of publication: | Weinheim |
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| Document Type: | Article |
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| Language: | English |
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| Date of Publication (online): | 2021/06/23 |
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| Date of first Publication: | 2020/04/03 |
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| Publishing Institution: | Ruhr-Universität Bochum, Universitätsbibliothek |
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| Tag: | covalent triazine frameworks; cyclotrimerization; nitrogen heterocycles; supercapacitors; waste prevention |
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| Volume: | 13 |
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| Issue: | 12 |
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| First Page: | 3192 |
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| Last Page: | 3198 |
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| Note: | Dieser Beitrag ist auf Grund des DEAL-Wiley-Vertrages frei zugänglich. |
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| Institutes/Facilities: | Lehrstuhl für anorganische Chemie I |
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| Dewey Decimal Classification: | Naturwissenschaften und Mathematik / Chemie, Kristallographie, Mineralogie |
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| open_access (DINI-Set): | open_access |
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| faculties: | Fakultät für Chemie und Biochemie |
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| Licence (English): |  Creative Commons - CC BY 4.0 - Attribution 4.0 International |
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