Selective surface oxidation and segregation upon short term annealing of model alloys and industrial steel grades

  • Segregation and selective oxidation phenomena of minor alloying elements during annealing of steel sheets lead to the formation of bare spots after hot-dip galvanizing. This thesis highlights the influence of annealing conditions and the effect of alloying elements on the selective oxidation in model alloys and some industrial steel grades. Model alloys of binary (Fe-2Si, Fe-2Mn, Fe-0.8Cr), ternary (Fe-2Mn-2Si, Fe-2Mn-0.8Cr, Fe-1Mn-0.8Cr, Fe-1Si-0.8Cr, Fe-2Si-0.8Cr) and quarternary (Fe-2Mn-2Si-0.8Cr) systems were studied. In the case of steels, standard grade interstitial free (IF) steels and experimental grade tensile strength 1000 MPa steel were investigated. All specimens were annealed at 820 °C in N\(_{2}\)-5%H\(_{2}\) gas atmospheres with the wide range of dew points (i.e. -80 to 0 °C). The surface chemistry after annealing and its wettability with liquid Zn have been correlated as a function of dew points by simulating the hot-dip galvanizing process at laboratory scale.

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Metadaten
Author:Srinivasan Swaminathan
URN:urn:nbn:de:hbz:294-20938
Referee:Andreas D. WieckORCiDGND, Michael SpiegelGND
Document Type:Doctoral Thesis
Language:English
Date of Publication (online):2008/01/09
Date of first Publication:2008/01/09
Publishing Institution:Ruhr-Universität Bochum, Universitätsbibliothek
Granting Institution:Ruhr-Universität Bochum, Fakultät für Physik und Astronomie
Date of final exam:2007/12/11
Creating Corporation:Fakultät für Physik und Astronomie
GND-Keyword:Segregation (Technik); Selektive Oxidation; Feuerverzinken; IF-Stahl; Legierung
Institutes/Facilities:Max-Planck-Institut für Eisenforschung, Düsseldorf
Dewey Decimal Classification:Naturwissenschaften und Mathematik / Physik
Licence (German):License LogoKeine Creative Commons Lizenz - es gelten der Veröffentlichungsvertrag und das deutsche Urheberrecht